ORGLIST: Selective Imine reduction

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From: vithal jadhav (vitli$##$rediffmail.com)
Date: Mon Jun 09 2008 - 01:23:31 EDT


  Dear Bhusan, In ur case it seems its difficult even with sodium borohydride. How if u can protect the aryl adehydr to acetal and carryout the reduction? All the best regards Vithal Jadhav On Sun, 08 Jun 2008 everybody-request$##$orglist.net wrote : >Send Everybody mailing list submissions to > everybody$##$orglist.net > >To subscribe or unsubscribe via the World Wide Web, visit > http://two.pairlist.net/mailman/listinfo/everybody >or, via email, send a message with subject or body 'help' to > everybody-request$##$orglist.net > >You can reach the person managing the list at > everybody-owner$##$orglist.net > >When replying, please edit your Subject line so it is more specific >than "Re: Contents of Everybody digest..." > > >Today's Topics: > > 1. Imine reduction (Bhushan Deodhar) > > >---------------------------------------------------------------------- > >Message: 1 >Date: Sat, 7 Jun 2008 17:26:58 -0400 > From: "Bhushan Deodhar" <bsdeodhar$##$gmail.com> >Subject: ORGLIST: Imine reduction >To: everybody$##$orglist.net >Message-ID: > <9107aac30806071426o86c216fyf3d6ab7795747a88$##$mail.gmail.com> >Content-Type: text/plain; charset=ISO-8859-1 > >Dear Members , > > I am trying to reduce a imine selectively in >presence of an aryl aldehyde which is part of the same molecule , iam >trying to use sodium cyanoborohydride for the same,but after i do the >work up i see that the aryl aldehyde also gets reduced to Ar-OH ,so >please help me on the above,can i use sodium borohydride to do the >same ,replies will be highly appreciated. > > >-- >Regards, > >Bhushan > > >------------------------------ > >_______________________________________________ >ORGLIST - Organic Chemistry Mailing List >Website / Archive / FAQ: http://www.orglist.net >To post a message (TO EVERYBODY) send to everybody$##$orglist.net >To unsubscribe, send to everybody-request$##$orglist.net the message: unsubscribe your_orglist_password your_address > >End of Everybody Digest, Vol 48, Issue 5 >****************************************


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