ORGLIST: Derivatives of N-vinylpyrrolidone, free reaction search engines

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From: cardman (cardman400$##$yahoo.com)
Date: Tue May 23 2006 - 19:47:06 EDT

Hi Everyone,

I'd like to know if functionalization at the alpha
position in N-vinylpyrrolidone is possible. Can one
form a stable enolate with, say, LDA, (or a milder,
nonnucleophilic base) and then either alkylate
directly or else hydroxylate or halogenate?
Or will one just wind up with polymer?

Also, is there a free searchable reaction database
akin to Crossfire/Beilstein? Organic Syntheses has
one, but it's not comprehensive. Thanks.

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