From: Chapman, Robert D n/a (robert.chapman$##$navy.mil)
Date: Tue May 23 2006 - 14:03:12 EDT
Dr. Hervé:
See the excellent review by Hansch et al.: http://pubs.acs.org/acs/journals/doilookup?in_doi=10.1021/cr00002a004
which cites an original reference for azide by Smith et al.: http://pubs.acs.org/acs/journals/doilookup?in_doi=10.1021/ja00862a033
Also see the article by Charton: http://pubs.acs.org/cgi-bin/abstract.cgi/joceah/1964/29/i05/f-pdf/f_jo01028a057.pdf
Sincerely,
Robert D. Chapman, Ph.D.
Chemistry Branch (Code 498200D)
Naval Air Warfare Center
1900 N. Knox Rd. Stop 6303
China Lake, CA 93555-6106 USA
-----Original Message-----
From: everybody-bounces$##$orglist.net [mailto:everybody-bounces$##$orglist.net]On Behalf Of HERVE Gregoire
Sent: May 23, 2006 7:10
To: everybody$##$orglist.net
Subject: ORGLIST: inductive and mesomeric effect of azide
Hi everybody,
I am searching inductive and mesomeric effect data regarding azide moiety. In the literature, I only found information about common groups such as NO2, COR, OR, and so... but nothing about N3. My first intuition is that N3 group should have a +M effect due to the negative charge located on the external nitrogens. How about its inductive effect?
I would greatly appreciate if somebody could help me in providing some recent bibliographic references dealing with these effects.
Thank you.
Grégoire HERVÉ
Responsable études synthèse
SME Centre de Recherches du Bouchet
Groupe SNPE
+33 (0)1 64 99 11 81
g.herve$##$snpe.com
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