ORGLIST: inductive and mesomeric effect of azide

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From: HERVE Gregoire (G.HERVE$##$snpe.com)
Date: Tue May 23 2006 - 10:10:28 EDT

Hi everybody,

 

I am searching inductive and mesomeric effect data regarding azide moiety. In the literature, I only found information about common groups such as NO2, COR, OR, and so... but nothing about N3. My first intuition is that N3 group should have a +M effect due to the negative charge located on the external nitrogens. How about its inductive effect?

 

I would greatly appreciate if somebody could help me in providing some recent bibliographic references dealing with these effects.

Thank you.

 

Grégoire HERVÉ
Responsable études synthèse
SME Centre de Recherches du Bouchet
Groupe SNPE
+33 (0)1 64 99 11 81
g.herve$##$snpe.com

 
 
 
 


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