ORGLIST: Fractional Distillation - seperation of mixtures

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From: fine chem (chemicals555$##$yahoo.com)
Date: Tue Apr 18 2006 - 04:56:01 EDT


Dear All,
   
  This goes out to those expert in fractional distillation : A mixture contains 2 organic liquids (completely miscible with each other), one with a boiling point of 80 deg C and the other with a boiling point of 35 deg C.
  Can the two liquids be completely seperated by fractional distillation using a very long column or will they behave as a binary azeotropic mixture at constant pressure (constant boiling point mixture) and the distillate still contain proportions of both mixtures ?
  I'am asking as I have not fully understood the concept; some say the mixtures are not seperable while others say the mixtures are completely seperable; am confused.
  jmarjorie
   
   
   

                
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