ORGLIST: DiBenzoyl Peroxide (DBP) - Addition Polymerization

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From: fine chem (chemicals555$##$yahoo.com)
Date: Wed Apr 12 2006 - 07:13:53 EDT


Would anyone know something about the following pertaining to DBP :
   
  1) Is it pH dependent in its polymerization catalytic activity
  2) Ideal temperature for optimum activity in liquid media
    with Ethanol as solvent (monomer dissolved in solvent)
  3) How good will DBP catalyse addition polymerization
    for the following in Ethanol as solvent :
    A) Isoprene (2-methyl buta-1,3-diene) C5H8
          CH2=C(CH3)CH=CH2
    
    B) Monoterpene (2,6-dimethyl octa-1,7-diene) C10H16
          CH2=C(CH3)CH.CH2.CH2C(CH3)CH=CH2
   
  4) Can Benzoyl Peroxide C6H5COOOH also work as well as DBP ?
  
Your kind assistance will be highly appreciated.
Thankyou,
  jmarjorie
   
   
   
   

                        
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