From: Ravi Orugunty (rorugunty$##$oragenics.com)
Date: Tue Mar 28 2006 - 13:13:29 EST
Hi Bill,
A mild quenching method for NaOCl would be dilute Iodine solution (this
reaction can be monitored colorimetrically, i.e add enough iodine till a
very faint orange color persists. I'm assuming that you are using the
reagent in water, Iodine is not very soluble in water, but you can
effectively dissolve Iodine by dissolving it an aqueous solution of
Potassium iodide(several formulas/receipes are available to make it).
The other reagents are ascorbic acid, KMnO4, thiourea or ferrous salts. I
think iodine is the quick and easy to monitor.
best regards
ravi
-----Original Message-----
From: everybody-bounces$##$orglist.net
[mailto:everybody-bounces$##$orglist.net]On Behalf Of
everybody-request$##$orglist.net
Sent: Tuesday, March 28, 2006 12:05 PM
To: everybody$##$orglist.net
Subject: Everybody Digest, Vol 19, Issue 22
Send Everybody mailing list submissions to
everybody$##$orglist.net
To subscribe or unsubscribe via the World Wide Web, visit
http://two.pairlist.net/mailman/listinfo/everybody
or, via email, send a message with subject or body 'help' to
everybody-request$##$orglist.net
You can reach the person managing the list at
everybody-owner$##$orglist.net
When replying, please edit your Subject line so it is more specific
than "Re: Contents of Everybody digest..."
Today's Topics:
1. A question (William Loffredo)
2. NaOCl quench (will jones)
----------------------------------------------------------------------
Message: 1
Date: Tue, 28 Mar 2006 08:46:21 -0500
From: "William Loffredo" <wloffredo$##$po-box.esu.edu>
Subject: ORGLIST: A question
To: <everybody$##$orglist.net>
Message-ID:
<6B0269EF2D64E840894D3B044D6586F802514C5D$##$fang.admin.esu.edu>
Content-Type: text/plain; charset="us-ascii"
Hello Everyone,
We are trying to synthesize a mixed anhydride in which one of
the sides is lauric acid and the other a short chain acid. I am trying
to locate a very viable synthetic procedure possibly using DCC or
another coupling agent. Can anyone help me locate the specific
literature sources? I would greatly appreciate it since the only two
articles I could find are in Japanese and we are trying to get them
translated.
Please reply directly to me at wloffredo$##$po-box.esu.edu
Dr. William M. Loffredo
Department of Chemistry
East Stroudsburg University
East Stroudsburg, PA 18301
(570) 422-3215
-------------- next part --------------
An HTML attachment was scrubbed...
URL:
http://two.pairlist.net/pipermail/everybody/attachments/20060328/ae7d5567/at
tachment-0001.html
------------------------------
Message: 2
Date: Tue, 28 Mar 2006 17:00:35 +0000
From: "will jones" <willjones46$##$hotmail.com>
Subject: ORGLIST: NaOCl quench
To: everybody$##$orglist.net
Message-ID: <BAY102-F2694A9B8070F43E9E4747BAED30$##$phx.gbl>
Content-Type: text/plain; format=flowed
hi guys
Thanks for the suggestions on how to quench H2O2.
Now for another quenching question. What is the best (and safest) way to
quench NaOCl?
I've seen urea used in a patent, but I'm concerned about NCl3 being
produced. My solution to quench is about 1mL of 5% NaOCl, so this isnt an
industrial problem. I just prefer to keep explosions out of the lab.
Any suggestions welcome.
Cheers for any help
Will
------------------------------
_______________________________________________
ORGLIST - Organic Chemistry Mailing List
Website / Archive / FAQ: http://www.orglist.net
To post a message (TO EVERYBODY) send to everybody$##$orglist.net
To unsubscribe, send to everybody-request$##$orglist.net the message:
unsubscribe your_orglist_password your_address
End of Everybody Digest, Vol 19, Issue 22
*****************************************
_______________________________________________
ORGLIST - Organic Chemistry Mailing List
Website / Archive / FAQ: http://www.orglist.net
To post a message (TO EVERYBODY) send to everybody$##$orglist.net
To unsubscribe, send to everybody-request$##$orglist.net the message: unsubscribe your_orglist_password your_address
This archive was generated by hypermail 2.1.4 : Tue Feb 13 2007 - 14:17:01 EST