ORGLIST: question on alkylation of cyclic beta-diketones

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From: 星海 王 (rickw9953$##$
Date: Thu Jun 23 2005 - 05:13:38 EDT

Dear all:
I am just work on alpha-alkylation of cyclic beta-diketones. as we know, the properities of cyclic beta-diketones is different from open-chain diketones, related to alpha-alkylation, in cyclic ones, the by product of o-alkylaltion is nearly unavoidable, even in high yield, As a whole, such regio-selectivity is influenced by several factors, including solvent, alkali, temperature and catalyst, but there is few comprehensive review on it. I expect to discuss this topic with you. Any reply is very appreciable.
Xinghai Wang. Ph.D. candidate
Department of Medicinal Chemistry,
School of Pharmacy,
Fudan University,
138 Yixueyuan Road,
Shanghai 200032, PR China


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