ORGLIST: Biphenyls via Grignard

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From: Paul Krebaum (adhesivedoc$##$earthlink.net)
Date: Sun Mar 20 2005 - 16:06:35 EST



Try adding Cu(I) or Ni(II) salts as catalyst with Gringnard reagents. You
might want to try the Ullman or Wurtz coupling reactions and skip the
Grignard formation entirely.
See March, "Advanced Organic Chemistry : Reactions, Mechanisms, and
Structure", 4th ed., Rxns. 0-86, 0-87, 3-16 (esp. refs. 193-199), 4-33,
4-34, and 4-35.

--- Paul Krebaum
--- adhesivedoc$##$earthlink.net



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