ORGLIST:Nitration...

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From: MIGUEL ANGEL MENDEZ ROJAS (mendezm$##$mail.udlap.mx)
Date: Thu Sep 25 2003 - 21:14:47 EDT


 I have been trying to nitrate an aromatic ring of
2,3-dichloro-naphtoquinone using a HNO3/H2SO4 mixture at 35°C. After two
hours, it seems like the starting material is still there and none (or a
minimal amount of nitrated product) is produced.
 Any suggestion. I don´t want to knock-out the chlorines...only nitrate
the aromatic ring.

 Thanks.

-----------------------------------------------------------------------------
 Dr. Miguel A. Méndez-Rojas
 Departamento de Química y Biología
 Escuela de Ciencias, Universidad de las Américas-Puebla
 Ex-Hda. de Sta. Catarina Martir, A.P. 100, Cholula 72820, Puebla, México
 Tel. 01 (222) 229 2067, Fax. 01 (222) 229 2419
 Tel. (directo) 01 (222) 229 2607 (Oficina 9-101)
 mendezm$##$mail.udlap.mx
-----------------------------------------------------------------------------

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