Re: ORGLIST:enolates

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From: Jacob Zabicky (zabicky$##$bgumail.bgu.ac.il)
Date: Sun Sep 14 2003 - 14:11:30 EDT

Dear Steve,

I cannot give you the reference you asked for, however, this very old
review may be helpful, as it includes a section on heterocyclic ketones
with O, N, and S atoms in the desired positions:

S. Forsen and M. Nilsson, "Enolization", in The Chemistry of the
Carbonyl Group, Vol. 2, J. Zabicky (ed.), Interscience, London, 1970,
pp.157ff.

All the best,

Jacob

On Sunday, Sep 14, 2003, at 00:51 Asia/Jerusalem, Steve P Lee wrote:

>
> Hi,
>
> I'm looking for a recent review that provides
> the results from enolization of unsymmetrical ketones
> with heteroatoms at the alpha position. I'm particularly
> interested in the ratios of kinetic vs. thermodynamic
> enolates generated, when there's a heteroatom at the
> alpha position.
>
> I have an older reference from 1979: Carbon-Carbon
> Bond Formation, edited by Robert Augustine.
>
> I'd appreciate any suggestions, since my library's
> resources are limited.
>
> Thanks.
>
> ---------------------------------
> Steve Lee, Ph.D.
> Assistant Professor of Chemistry
> Roosevelt University
> Chicago and Schaumburg, IL
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***************************************************
Prof. Jacob Zabicky
Institutes for Applied Research
Ben-Gurion University of the Negev
P. O. Box 653, Beer-Sheva, 84105, Israel

Phone: +972-8-6461271; Fax: +972-8-6472969
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