From: Ismail, Fyaz (F.M.Ismail$##$livjm.ac.uk)
Date: Tue Jul 08 2003 - 14:58:01 EDT
di-tert-butylamine, [21981-37-3]
The photochemical reduction of di-tert-butyl nitroxide to di-tert-butylamine
can be achieved in 65% yield [1]. Di-t-Butyl Nitroxide can be prepared
using a checked procedure [2]. Other synthetic procedures to
di-tert-butylamine are also known [3].
References
[1] Kornblum, N. Pinnick, H. W. Reduction of nitroxides to amines by sodium
sulfide. J. Org. Chem.; 1972; 37(12); 2050-2051; [2] Submitted by A. K.
Hoffmann, A. M. Feldman, E. Gelblum, and A. Henderson1; Checked by R. A.
Haggard and William D. Emmons. Organic Syntheses, CV 5, 355 ] and can be
accessed on line from www.orgsyn.org.; [3] a) Klages, F; Sits, H. Ber. 92,
2606 (1959); b) N. C. Deno, N.C.; Fishbein, R.; Wyckoff, and J. C. J. Amer.
Chem. Soc., 93, 2066 (1971).
Kindest Regards,
Dr. Fyaz M.D. Ismail
Programme and Research Leader
The Medicinal Chemistry Research Group
The School of Pharmacy and Chemistry
Liverpool John Moores University
Room 221C James Parsons Building
Byrom Street
Liverpool L3 3AF
Telephone: +44 (0)151 231 2231.
-----Original Message-----
From: Bel [mailto:suzukicar$##$belais.freesurf.fr]
Sent: 08 July 2003 09:17
To: everybody$##$orglist.net
Subject: ORGLIST:di-tert-butylamine
Dear all,
I looked for di-tert-butylamine in all available catalogues that we have
and It seems that this reagent is not commercially available. Does anyone
know how to make It? or Do you know any company which sell It?
Thanks in advance
Cheers
Bel
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