ORGLIST:Re: Everybody digest, Vol 1 #220 - 2 msgs

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From: David Kelly (KellyDR$##$Cardiff.ac.uk)
Date: Thu May 29 2003 - 13:05:51 EDT

Dichloromethane and tertiary amines

These slowly form the the methylene chloride derivative ie
[R3NCH2Cl]+ Cl-. It is a substantial problem with the more nucleophilic
amines such as DABCO or quinuclidine over periods of a week or
more.

Dave Kelly

Dr David R. Kelly
Dept. of Chemistry, Cardiff University, PO Box 912, Cardiff, CF10
3TB, UK
Phone 02920-874063: Fax 02920-874030
Mobile 07971-240448: Home 02920-610891
Web page http://www.cf.ac.uk/uwc/chemy/staff/kelly.html
For the "Elephants and Butterflies" article see
http://www.semiochemica.org.uk/articles/articlesidx.html
BEST Record: http://expertise.cos.com/cgi-bin/exp.cgi?id=498275
For catalysis see http://www.chemsoc.org/cgi-
shell/events/nforedisp.pl?ID=551
Cardiff University is the public name of the University of Wales,
Cardiff, a constituent institution of the
University of Wales.

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