From: Research Scholars,tpr (tprscrs$##$uohyd.ernet.in)
Date: Thu May 08 2003 - 00:13:05 EDT
Dear all
i tried reducing one longchain(c18) secondary amide with NaBH4/I2.
the reaction went through properly and i got the amine-borane complex, but
when i tried to cleave this with peroxide it went in some other way and i
could not get the final secondary amine( in the IR spectra the
corresponding peak for the amine-borane complex is disappeared) . can you
suggest me a definite way to cleave this kind of amine- borane complexes(
longchain).
thank you in advance
M. SHARATH CHANDRA
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Research Scholar Email:tprscrs@
Prof. T.P.Radhakrishnan's Group uohyd.ernet.in
Theoretical & Material's Chemistry Group Tel:(040)-23011068
School of Chemistry (040)-23010500
University of Hyderabad extn: 4827 & 4750
Hyderabad-500 046 FAX:91-40-23012460
India
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