RE: ORGLIST:sigma hammett

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From: J.N.Iley (J.N.Iley$##$open.ac.uk)
Date: Fri Nov 08 2002 - 07:28:24 EST


The value for sigma para for the ethynyl group is 0.23 (from Corwin Hansch's
compendium and from Perrin Dempsey and Serjeant)

Jim

> -----Original Message-----
> From: samarium Steiner [SMTP:neptunium$##$gmx.net]
> Sent: 07 November 2002 08:14
> To: everybody$##$orglist.net
> Subject: ORGLIST:sigma hammett
>
> Hi!
>
> I'm looking for the sigma hammett constant of the ethinyl-group attached
> on
> a aromatic nucleus (para position to an attached alkyl side chain).
> The computational program ACD/Sigma Pro can calculate this, but I have no
> account to this program.
>
> Thanks for helping!
>
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