Re: ORGLIST:simmons-smith reaction

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From: chemelf$##$gmx.net
Date: Thu Oct 10 2002 - 07:29:50 EDT


No, due to b-elimination ICH2CHI will form ethene, as to ICH2CH2CH2I
cyclopropane (C3H6) is very possible product.

Ilfir
http://chemelf.tripod.com

Thursday, October 10, 2002, 12:27:48 PM, you wrote:

J> Dear collegues,
J> Reffering to the above named reaction
J> that traditionally gives cyclopropanes with an alkene
J> where the active reagent is ICH2I (simmons reagent),
J> Can the reagent be varied to,say, ICH2CH2I so as to
J> give a cyclobutane; ICH2CH2CH2I to give cyclopentane?
J> jaininder2002$##$yahoo.com

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