RE: ORGLIST:An esterification that will not proceed!

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From: Jim Mitchell (j_mitchell$##$cerilliant.com)
Date: Sun Sep 08 2002 - 12:27:55 EDT


You should try 2eq of H2SO4 and reflux overnight, that should do the trick.

Jim Mitchell
Cerilliant Corporation

-----Original Message-----
From: Badru Nsubuga [SMTP:bdnsubuga$##$yahoo.co.uk]
Sent: Saturday, September 07, 2002 5:10 PM
To: everybody$##$orglist.net
Subject: ORGLIST:An esterification that will not proceed!

Reaction of 4-hydroxy-3-methoxybenzoic acid (vanillic
acid, VA) with absolute ethanol in the presence of
catalytic amounts of sulfuric acid, will not produce
enough ethyl-4-hydroxy-3-methoxybenzoate! Does anyone
know why? What is the pKa of VA?

Save me that trip to the library! Thanks.

Badru

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