From: JSM (jaininder2002$##$yahoo.com)
Date: Tue Aug 13 2002 - 03:28:39 EDT
Dear sir/Madam,
I'am an amateur scientist in Africa and
access to information and expert opinion is not
available.I have a perplexing question.I would like to
know if a Reformatsky reaction is possible between a
linear a-bromoester and a Nitrogen containing
cis-diketone.(eg. N-Butyl Phthalimide).The nitrogen is
fully bonded; all single linkages and non polar.
This type of reaction is not listed anywhere.All the
available literature is on C,H,O compounds containing
a single keto-group.
- Will the Nitrogen interefere in anyway(If so, how
can this be counteracted?)
- Which combination of reagents which are fairly
common, inexpensive, simple to work with and give high
yields could be used(Including reaction conditions and
journal article references)
- Can Electrosynthesis or Microwave oven be
used;bearing all the above in mind?
- Will the final product have the a-bromoesters in the
cis-position or some in the trans-positions?
Any assistance will be highly appreciated.Please help.
My e-mail : jaininder2002$##$yahoo.com
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