RE: ORGLIST: Diastereotopic shifts

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From: Roux, Stephane (RouxS$##$corning.com)
Date: Fri May 03 2002 - 09:05:45 EDT


Yes, I saw that in C60 derivatives between a hydrogen just above the surface
and the other one in a C60-retinol A adduct.

-----Message d'origine-----
De : Plamen Angelov [mailto:angelov$##$argon.acad.bg]
Envoye : vendredi 3 mai 2002 10:49
A : Multiple recipients of list orglist
Objet : ORGLIST: Diastereotopic shifts

Dear all,
It is well known that diastereotopic protons give differently shifted
signals in the 1H-NMR spectrum, but what about difference as great as 1 -
1.5 ppm? Do you think it is possible and has anyone ever observed such a
fenomenon?

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