Dear Colleauges, I wish to perform chloromethylation on my bromobenzene. can anyone please give me some helpful procedures to start on? the theoretical step is as follows: ZnCl2 ArBr + HCHO + HCl(g)------------> (CH2Cl)2C6H3Br wonder if I still need to use ZnCl2 if an electron donating group is attached to the ring such as -OR group? and what's the function of ZnCl2? (is it added in catalytic amount?) I would very much appreciate it if anyone could contribute the working procedures to get this reaction started. Thanks in advance, Barnabas. Get Your Private, Free Email at http://www.hotmail.com __________________ ORGLIST - Organic Chemistry Mailing List WWW Homepage and Archive: http://www.orglist.net/ List coordinator: Joao Aires de Sousa (jas@mail.fct.unl.pt)