Re: ORGLIST: wittig reaction

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From: Camacho Davila Alejandro Alberto (acamacho$##$pasteur.fcq.uach.mx)
Date: Fri Oct 22 1999 - 05:17:59 EDT


Indeed, the Wittig reaction with esters and other carbonyl compounds is
possible, more detailed information could be consulted in the following
review article:

P.J. Murphy and J. Brennan
The Wittig Olefination Reaction with carbonyl compounds other than
aldehydes and ketones.
Chem. Soc. Rev. 17: 1-30 (1988).

Sincerely


**********************************
Alejandro Camacho-Davila *
Facultad de Ciencias Quimicas *
Universidad Autonoma de Chihuahua*
Apartado Postal 1542-C *
Chihuahua, Chih. 31110 *
MEXICO *
**********************************

On Fri, 22 Oct 1999, barnabas liau wrote:

> Dear colleagues,
> I have a weird idea. wittig reaction can be easily performed on ketone or
> aldehyde. can anyone please tell me if is possible for a cyclic ester?! if
> not, is it because the reaction simply can't happen or fear of hydrolysis
> (saponification) that may take place?
> Please advice and thanks in advance.
>
> Regards,
> barnabas
>
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