From: Daničle REYX (reyx$##$lola.univ-lemans.fr)
Date: Fri Jun 25 1999 - 05:38:56 EDT
The corresponding N,N diethyl compounds were previously described. See the
following paper : M. Thomas and D. Reyx, New J. Chem., 14, 651 (1990) and
its biblio, especially refs. 11-13
>Hi everyone,
>
>
>Does anyone know a way to synthesize monosilylated secondary silylamines,
>like chlorodimethylsilyl-(N,N-diisopropyl)amine Cl(Me)2SiN(iPr)2 and of
>course related compounds? I have tried to do this by reacting Cl2Me2Si with
>2 eq HN(iPr)2, but I keep ending up with the disilylated product and lots
>(half?) of the unreacted starting
>materials.
>
>
>The only article I found about these compounds (J. Organomet. Chem 18, 371
>(1969)) had no experimental, but refered to an unpublished article (which
>was probably never published at all). If you know to make these materials
>(pure & high yield) please answer
>
>
>Thanks, thanks, thanks,
>Rob Hanssen <r.w.j.m.hanssen$##$tue.nl>
>
>__________________
>
>ORGLIST - Organic Chemistry Mailing List
>Website and Archive: http://www.orglist.net/
>List coordinator: Joao Aires de Sousa (jas$##$mail.fct.unl.pt)
Pr Daničle REYX (Mme)
Laboratoire de Chimie Organique Macromoleculaire
UMR CNRS N°6515
Universite du Maine
Av. Olivier-Messiaen
72085 LE MANS Cedex 9
FRANCE
Fax 33 2 43 83 37 54
Tel 33 2 43 83 35 40 (ou 33 30)
__________________
ORGLIST - Organic Chemistry Mailing List
Website and Archive: http://www.orglist.net/
List coordinator: Joao Aires de Sousa (jas$##$mail.fct.unl.pt)
This archive was generated by hypermail 2.1.4 : Fri Sep 19 2003 - 12:15:04 EDT