EI spectra of 2,4-octadiyne-1-ol (MW=120) shows prominent peaks = at 66, 77, 91 (also 105, 107, 122) and 183, 310 (probably collision = peaks). Homologous compounds give similar spectra. I would be grateful if someone with experience in MS spectra = interpretation could help me explain the fragmentations/reactions = leading to the 66, 77, 91, 183 and 310 peaks. Any hint appreciated ! Thank you in advance ! Eugen B. Chem.Dept. Univ. of Ploiesti, RO __________________ ORGLIST - Organic Chemistry Mailing List WWW Homepage and Archive: http://www.orglist.net/ List coordinator: Joao Aires de Sousa (jas@mail.fct.unl.pt)