ORGLIST: Cl3SiLi

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From: Timothy L. Friebe (tlf5$##$psu.edu)
Date: Thu Jun 12 1997 - 15:06:29 EDT


I am currently in need of a method for synthesizing primary alkyl
trichlorosilanes preferably without adding H-SiCl3 across a double bond.
Is it possible to generate Li-SiCl3 (from H-SiCl3 and n-BuLi) and then do
an SN2 reaction on a primary alkyl tosylate? The alkyl group desired
already has an internal double bond which would cause problems when doing a
hydrosilation. Any help would be appreciated! Thanks in advance.

Tim Friebe

Timothy L. Friebe
PennState-Erie, Behrend College
Division of Science
Erie, PA 16563
(814) 898-6411
tlf5$##$psu.edu


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