From: Timothy L. Friebe (tlf5$##$psu.edu)
Date: Thu Jun 12 1997 - 15:06:29 EDT
I am currently in need of a method for synthesizing primary alkyl
trichlorosilanes preferably without adding H-SiCl3 across a double bond.
Is it possible to generate Li-SiCl3 (from H-SiCl3 and n-BuLi) and then do
an SN2 reaction on a primary alkyl tosylate? The alkyl group desired
already has an internal double bond which would cause problems when doing a
hydrosilation. Any help would be appreciated! Thanks in advance.
Timothy L. Friebe
PennState-Erie, Behrend College
Division of Science
Erie, PA 16563
ORGLIST - Organic Chemistry Mailing List
WWW Homepage and Archive: http://www.orglist.net/
List coordinator: Joao Aires de Sousa (jas$##$mail.fct.unl.pt)
This archive was generated by hypermail 2.1.4 : Fri Sep 19 2003 - 12:14:31 EDT